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ทังสเตนคาร์ไบด์

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ทังสเตนคาร์ไบด์
       ทังสเตนคาร์ไบด์ (อังกฤษ: tungsten carbide) มีสูตรเคมีคือ WC ในรูปพื้นฐานจะมีลักษณะเป็นผงสีเทาละเอียด มี 2 โครงสร้างคือแบบหกเหลี่ยม (α-WC) และแบบลูกบาศก์ (β-WC)
 
       ทังสเตนคาร์ไบด์เตรียมได้จากการทำปฏิกิริยาระหว่างทังสเตนกับคาร์บอนที่อุณหภูมิ 1400–2000 °C[3] หรือให้ความร้อนกับทังสเตนไตรออกไซด์และแกรไฟต์โดยตรงที่ 900 °C หรือในแก๊สไฮโดรเจนที่ 670 °C ตามด้วยการคาร์บิวไรเซชันในแก๊สอาร์กอนที่ 1000 °C[4] หรือใช้วิธีการเคลือบด้วยไอเคมี เช่น
  • ทำปฏิกิริยาระหว่างทังสเตนเฮกซะคลอไรด์กับไฮโดรเจนและมีเทนที่อุณหภูมิ 670 °C (1,238 °F)
 WCl6 + H2 + CH4 WC + 6 HCl
  • ทำปฏิกิริยาระหว่างทังสเตนเฮกซะฟลูออไรด์กับไฮโดรเจนและเมทานอลที่อุณหภูมิ 350 °C (662 °F)
                WF6 + 2 H2 + CH3OH → WC + 6 HF + H2O
       ทังสเตนคาร์ไบด์มีจุดหลอมเหลวที่ 2,870 °C (5,200 °F) และจุดเดือดที่ 6,000 °C (10,830 °F) มีความแข็งระดับ 9 ตามมาตราโมสและประมาณ 2600 ตามมาตราวิกเคอส์[5] ทังสเตนคาร์ไบด์มีความแข็งเกร็งมากกว่าเหล็กกล้าประมาณ 2 เท่า มีค่ามอดุลัสของยังประมาณ 530–700 GPa (77,000–102,000 ksi)[2][6][5][7] โมดูลัสของแรงบีบอัด 630–655 GPa และโมดูลัสของแรงเฉือน 274 GPa[8]
 
ด้วยคุณสมบัติความแข็งและทนความร้อนสูง ทังสเตนคาร์ไบด์จึงใช้ทำเป็นเครื่องมือตัดหรือหัวเจาะ ใช้ทำกระสุนเจาะเกราะ เครื่องมือผ่าตัด อุปกรณ์กีฬา เครื่องประดับและอื่น ๆ
 
 
 
 
 
 
 
 
 
 
อ้างอิง
 
  1. Kurlov, p. 22
  2. Blau, Peter J. (2003). Wear of Materials. Elsevier. p. 1345. ISBN 978-0-08-044301-0.
  3. Pierson, Hugh O. (1992). Handbook of Chemical Vapor Deposition (CVD): Principles, Technology, and Applications. William Andrew Inc. ISBN 0-8155-1300-3.
  4. Zhong, Y.; Shaw, L. (2011). 'A study on the synthesis of nanostructured WC–10 wt% Co particles from WO3 , Co3O4 , and graphite'. Journal of Materials Science 46 (19): 6323–6331. Bibcode:2011JMatS..46.6323Z. doi:10.1007/s10853-010-4937-y.
  5. Groover, Mikell P. (2010). Fundamentals of Modern Manufacturing: Materials, Processes, and Systems. John Wiley & Sons. p. 135. ISBN 978-0-470-46700-8.
  6. Kurlov, p. 3
  7. Cardarelli, François (2008). Materials Handbook: A Concise Desktop Reference. Springer Science & Business Media. pp. 640–. ISBN 978-1-84628-669-8.
  8. Kurlov, pp. 30, 135
  9. Sprince, NL.; Chamberlin, RI.; Hales, CA.; Weber, AL.; Kazemi, H. (1984). 'Respiratory disease in tungsten carbide production workers'. Chest 86 (4): 549–557. PMID 6434250. doi:10.1378/chest.86.4.549.
  10. 12th Report on Carcinogens'. National Toxicology Program. http://ntp.niehs.nih.gov/go/roc12. เรียกข้อมูลเมื่อ 2011-06-24.
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Capable and sensible jaipur call girls service satisfies you the way wherein you need as the master and sensible young call girl you pick grant you like lovemaking practices like foreplay. Foreplay is a higher need than peak or intercourse. Closeness in different sexual positions and moves work on the fun and bliss while lovemaking. Embracing, kissing, reaching, goading, touching, and mumbling are uncommonly fundamental pieces of lovemaking. Sexual position makes entire lovemaking brassy and it stimulates you more.

 
neha singh [182.64.193.xxx] เมื่อ 26/09/2022 18:49
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elraqi [196.221.215.xxx] เมื่อ 26/09/2022 21:26
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