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ทังสเตนคาร์ไบด์

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ทังสเตนคาร์ไบด์
       ทังสเตนคาร์ไบด์ (อังกฤษ: tungsten carbide) มีสูตรเคมีคือ WC ในรูปพื้นฐานจะมีลักษณะเป็นผงสีเทาละเอียด มี 2 โครงสร้างคือแบบหกเหลี่ยม (α-WC) และแบบลูกบาศก์ (β-WC)
 
       ทังสเตนคาร์ไบด์เตรียมได้จากการทำปฏิกิริยาระหว่างทังสเตนกับคาร์บอนที่อุณหภูมิ 1400–2000 °C[3] หรือให้ความร้อนกับทังสเตนไตรออกไซด์และแกรไฟต์โดยตรงที่ 900 °C หรือในแก๊สไฮโดรเจนที่ 670 °C ตามด้วยการคาร์บิวไรเซชันในแก๊สอาร์กอนที่ 1000 °C[4] หรือใช้วิธีการเคลือบด้วยไอเคมี เช่น
  • ทำปฏิกิริยาระหว่างทังสเตนเฮกซะคลอไรด์กับไฮโดรเจนและมีเทนที่อุณหภูมิ 670 °C (1,238 °F)
 WCl6 + H2 + CH4 WC + 6 HCl
  • ทำปฏิกิริยาระหว่างทังสเตนเฮกซะฟลูออไรด์กับไฮโดรเจนและเมทานอลที่อุณหภูมิ 350 °C (662 °F)
                WF6 + 2 H2 + CH3OH → WC + 6 HF + H2O
       ทังสเตนคาร์ไบด์มีจุดหลอมเหลวที่ 2,870 °C (5,200 °F) และจุดเดือดที่ 6,000 °C (10,830 °F) มีความแข็งระดับ 9 ตามมาตราโมสและประมาณ 2600 ตามมาตราวิกเคอส์[5] ทังสเตนคาร์ไบด์มีความแข็งเกร็งมากกว่าเหล็กกล้าประมาณ 2 เท่า มีค่ามอดุลัสของยังประมาณ 530–700 GPa (77,000–102,000 ksi)[2][6][5][7] โมดูลัสของแรงบีบอัด 630–655 GPa และโมดูลัสของแรงเฉือน 274 GPa[8]
 
ด้วยคุณสมบัติความแข็งและทนความร้อนสูง ทังสเตนคาร์ไบด์จึงใช้ทำเป็นเครื่องมือตัดหรือหัวเจาะ ใช้ทำกระสุนเจาะเกราะ เครื่องมือผ่าตัด อุปกรณ์กีฬา เครื่องประดับและอื่น ๆ
 
 
 
 
 
 
 
 
 
 
อ้างอิง
 
  1. Kurlov, p. 22
  2. Blau, Peter J. (2003). Wear of Materials. Elsevier. p. 1345. ISBN 978-0-08-044301-0.
  3. Pierson, Hugh O. (1992). Handbook of Chemical Vapor Deposition (CVD): Principles, Technology, and Applications. William Andrew Inc. ISBN 0-8155-1300-3.
  4. Zhong, Y.; Shaw, L. (2011). 'A study on the synthesis of nanostructured WC–10 wt% Co particles from WO3 , Co3O4 , and graphite'. Journal of Materials Science 46 (19): 6323–6331. Bibcode:2011JMatS..46.6323Z. doi:10.1007/s10853-010-4937-y.
  5. Groover, Mikell P. (2010). Fundamentals of Modern Manufacturing: Materials, Processes, and Systems. John Wiley & Sons. p. 135. ISBN 978-0-470-46700-8.
  6. Kurlov, p. 3
  7. Cardarelli, François (2008). Materials Handbook: A Concise Desktop Reference. Springer Science & Business Media. pp. 640–. ISBN 978-1-84628-669-8.
  8. Kurlov, pp. 30, 135
  9. Sprince, NL.; Chamberlin, RI.; Hales, CA.; Weber, AL.; Kazemi, H. (1984). 'Respiratory disease in tungsten carbide production workers'. Chest 86 (4): 549–557. PMID 6434250. doi:10.1378/chest.86.4.549.
  10. 12th Report on Carcinogens'. National Toxicology Program. http://ntp.niehs.nih.gov/go/roc12. เรียกข้อมูลเมื่อ 2011-06-24.
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Vous devez le faire même si des symptômes de malaise ou d'intoxication n'ont pas été manifestés tout de suite. Vous pouvez avoir besoin de soins médicaux urgents. Habituellement, les symptômes de surdose comprennent une douleur thoracique, une vision brouillée, l’anxiété, une confusion, une pression artérielle extrêmement basse, une syncope, des palpitations. Ce médicament est conservé dans un endroit frais et sec, loin des sources de lumière du soleil, de la chaleur et de l'humidité. Ne le conservez pas dans la salle de bain. Gardez ce produit hors de la portée des enfants et des animaux domestiques. L’information présentée sur le site a un caractère général. Notez s'il vous plaît que cette information ne peut pas être utilisée pour l’ auto-traitement et l’auto-diagnostique. Vous devriez consulter avec votre médecin ou votre conseiller en santé concernant toute instruction spécifique de votre condition. L’information est fiable, mais nous admettons qu’elle peut contenir des erreurs. 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